After your diet and training are in check it is time to supplement. Prior to using exotic supplements, prohormones, test boosters, natural anabolics, insulin sensitizers, etc. you should have your staple supplement regiment down.

Supplements: Multi-vitamin, protein, carb supp, vit e, vit a, vit c, ZMA, glutamine, BCAAs.

Upon Waking: Multi-vitamin and protein shake as soon as your feet hit the floor.
Since you have an empty stomach and are in a depleted state. A fast acting protein along with a muti-vitamin will absorb fairly fast and take your body out of its starved catabolic state. This will also provide your body nutrients while you are getting ready and making breakfast.

Post Work Out: Protein, Carb supplement, 5g Glutamine, 5g BCAA and 1g Vit C in water
Excluding fat from this meal will promote faster and more complete absorption of the protein, carbs and vit c. The carbs will spike insulin promoting uptake of aminos and vit C to the blood stream. The aminos will be used to help build muscle, and the vit C will help reduce oxidative stress produced from training.

First Fat Containing Meal Post Work Out: Vit E and Vit A
Vitamin E and A will also help to prevent oxidative stress from training. Consuming them with a fat containing meal will promote absorption of these fat soluble vitamins.

45 Mins Before Bed: 5g Glutamine, 5g BCAA, 1g Vit C, and ZMA

Directly Before Bed: Protein Shake